How Did Pauli Derive the Pauli Matrices

In 1920s, Pauli faced the problem to solve properties of electrons:

  1. Magnetic behavior like a tiny bar magnet
  2. Two-valued “intrinsic” angular momentum (spin up / spin down)
  3. Spectral line splittings (Zeeman effect) that orbital angular momentum alone could not explain

So Pauli needed a mathematical object that:

  • Acts like angular momentum
  • But has only two internal states
  • Works inside Schrödinger’s quantum mechanics

Experiments of measuring spinor S on z axis, i.e. Sz yield two outputs; +z and -z, half and half:

Note Pauli matrices describe spin, but the physical spin operator includes the factor /2\hbar/2.

Spinor matrix combined with h/2 is spinor operator S!

It’s essential to understand the concept of spinor operator, spinor quantum state/electron, and <Svector>, with the following concrete example.

the spinor/electron is in this quantum state:

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